Lithium Village is a city in the Perry County, Missouri, United States. According to the 2000 census it had a population of 0 inhabitants. It is the smallest by population in the U.S. state of Missouri. Its area is just over 0 square miles (0 kmē), it is the smallest by area in the U.S. state of Missouri.
As of the census of 2000, there were people, 0 households, and 0 families residing in the city. The population density was 0 people per square mile (0/kmē), giving it the least densely populated city among the Missouri. There were 1 housing units at an average density of 0 per square mile (0/kmē). The average household size was 0 persons, and the average family size was 0 persons. In the Lithium Village, 0% of the population was under the age of 18, 0% were 18 to 24, 0% were 25 to 44, 0% were 45 to 64, and 0% who were 65 or older. For every 100 females there were 0 males. For every 100 females age 18 and over, there were 0 males. The median age was 0 years, The median age of males and females living in Lithium Village was 0 and 0 years respectively. The racial makeup of the city was White, Black or African American, American Indian, Asian, Native Hawaiian, from two or more races and Ohter races.